Engine Operational
GATE CH 2020 (with Solutions).pdf

Q24

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The operating temperature range for the Haber process is 350 - 500°C. It is used for the production of ammonia at

Options

  1. A.
    20 MPa using Fe catalyst in an exothermic reaction
  2. B.
    0.1 MPa using Fe catalyst in an exothermic reaction
  3. C.
    20 MPa using Fe catalyst in an endothermic reaction
  4. D.
    20 MPa using zeolite catalyst in an endothermic

Answer

A

Solution

The iron catalyst is used with added promoters for ammonia synthesis e.g. aluminum oxides, zirconium or silicone. These prevent sintering, and the catalyst becomes more porous. Iron catalysts quickly lose their activity, when heated above 520 ° C. Depending on the conversion required the pressure is around 100 - 1000 atm. Hence, the correct option is (A).

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